SC/CHEM 3011.04 Lecture Notes
INTRODUCTION .
Overview .
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I. EMPIRICAL KINETICS
Why Study Chemical Kinetics?
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I.1 Monitoring Chemical Change
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I.2 Rates
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I.3 Rate Laws
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I.4 Reaction Order
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I.5 Specific Reaction Rate
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I.6 Integrated Rate Laws
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I.7 Half-Life Method
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I.8 Summary
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II REACTION MECHANISMS
Assignment of Mechanism
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II.1 Simple (Elementary Reactions)
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II.2 Opposing Reactions
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II.3 Consecutive Reactions
II.3.1 Variations of Concentrations with Time
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II.3.2 Rate-Determining Step
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II.3.3 Steady-State Approximation
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II.3.4 Pre-Equilibrium
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II.4 Catalysed and Enzyme-Catalysed Reactions
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II.5 Unimolecular Reactions
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III COMPLEX REACTIONS
III.1 Chain Reactions
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III.2 Explosions
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III.3 Photochemical Reactions
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III.4 Polymerization Kinetics
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III.5 Catalysis and Oscillation
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III.6 Reactions in Solution
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IV ELEMENTARY REACTION RATE THEORY
IV.1 Collision Rate Theory
IV.1.1 Hard-Sphere Collision Frequency
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IV.1.2 Collision Rate Constant
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IV.1.3 "Harpoon" Reactions
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IV.2 Activated-Complex Theory
IV.2.1 Derivation of Eyring Equation
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IV.2.2 Application of Eyring Equation
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IV.2.4 Thermodinamic Formulation of the Eyring Equation
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IV.2.5 Isotope Effects
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V DYNAMIC ELECTROCHEMISTRY
V.1 Rate of Charge Transfer
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V.1.1 The Double Layer at the Interface: Helmholtz,
Gouy-Chapman, and Stern models
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V.1.2 The Rate of Charge Transfer under Zero Field: the chemical
rate constant
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V.1.3 The Butler-Volmer Equation: two limiting forms, Tafel plots
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V.1.4 Concentration Polarization
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V.1.5 Application in Polarography
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V.2 Cell EMF and Electric Current
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V.3 Corrosion
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